INDUSTRIAL HERITAGE AND PLACE IDENTITY IN SPAIN: FROM MONUMENTS TO LANDSCAPES*

In Spain, the birth of interest in the nation's industrial heritage dates from the 1980s and occurred alongside the process of deindustrialization. Policies concerning derelict industrial sites have shifted gradually from destruction to preservation, rehabilitation, and enhancement, and industrial heritage enhancement projects are now widespread in the country. However, a clear mismatching has arisen between institutional and academic initiatives and local communities, which exhibit widespread disinterest in or even rejection of industrial remains. This problematic situation can be related to the utilization of industrial heritage as an economic resource without paying much attention to its connections with memory and identity. Also, the mismatching is due to a positivist approach to industrial heritage whereby the monument and the museum are prioritized. We argue that projects which consider industrial remains as part of cultural landscapes might shorten the gap between the institutional and economic side of industrial heritage and its identity‐building and popular facets.     

Flow Behavior of Clay-Silt to Sand-Silt Water-Rich Suspensions at Low to High Shear Rates: Implications for Slurries, Transitional Flows, and Submarine Debris-Flows

Water-rich clay to sand suspensions show a shear rate dependent flow behavior and knowledge of the appropriate rheological model is relevant for sedimentological, industrial and hydraulic studies. We present experimental rheological measurements of water-rich (40 to 60 wt%) clay to silt (population A) and silt to sand (population B) suspensions mixed in different proportions. The data evidence a shear rate dependent shear thinning-shear thickening transition. At lower shear rates, the suspensions organize in chains of particles, whereas at higher shear rates, these chains disrupt so increasing the viscosity. The viscosity, consistency and yield stress decrease as the A+B fraction decreases as the content of B particles increases. This behavior reflects the competing effects of the lubrication and frictional processes as a function of particle size and water content. Transitional flows form by the incorporation of small amounts of the finer fraction while ‘oceanic floods’ form at the estuary of rivers and the submarine debris-flows increase their velocity by incorporating water. The critical Reynolds number of the studied suspensions is ~2000±100 suggesting that the grainsize plays a major role in the laminar to turbulent transition. Our results have implications for the modeling of sediment flows and the hazard related to floods.     

Review of the El Soplao Amber Outcrop,Early Cretaceous of Cantabria,Spain

<正>El Soplao outcrop,an Early Cretaceous amber deposit recently discovered in northern Spain (Cantabria),has been shown to be the largest site of amber with arthropod inclusions that has been found in Spain so far.Relevant data provided herein for biogeochemistry of the amber,palynology,taphonomy and arthropod bioinclusions complement those previously published.This set of data suggests at least two botanical sources for the amber of El Soplao deposit.The first(type A amber)strongly supports a source related to Cheirolepidiaceae,and the second(type B amber)shows non-specific conifer biomarkers.Comparison of molecular composition of type A amber with Frenelopsis leaves(Cheirolepidiaceae)strongly suggests a biochemical affinity and a common botanical origin.A preliminary palynological study indicates a regional high taxonomical diversity,mainly of pteridophyte spores and gymnosperm pollen grains.According to the preliminary palynological data,the region was inhabited by conifer forests adapted to a dry season under a subtropical climate.The abundant charcoalified wood associated with the amber in the same beds is evidence of paleofires that most likely promoted both the resin production and an intensive erosion of the litter,and subsequent great accumulation of amber plus plant cuticles.In addition,for the first time in the fossil record, charcoalified plant fibers as bioinclusions in amber are reported.Other relevant taphonomic data are the exceptional presence of serpulids and bryozoans on the surfaces of some amber pieces indicating both a long exposure on marine or brackish-water and a mixed assemblage of amber.Lastly,new findings of insect bioinclusions,some of them uncommon in the fossil record or showing remarkable adaptations,are reported.In conclusion,a documented scenario for the origin of the El Soplao amber outcrop is provided.     

Spatially varied soil erosion under different climates

Abstract

The spatial variability of the factors of the universal soil loss equation is examined on the mediterranean basin of Conca de Tremp covering 43.1 km² in Spain. The evaluation of the rainfall erosivity R and the soil erodibility K is relatively straightforward and spatially-averaged values of these parameters can be applied to the entire basin. Conversely, the spatial variability of annual soil erosion losses on large basins depends primarily on the factors L, S and C describing topographic, vegetation and land use parameters. A grid size analysis of soil erosion losses from the Conca de Tremp basin under mediterranean climatic conditions in Spain shows excellent agreement with the earlier results on the Chaudière basin in Canada. It is concluded for both basins that unbiassed estimates of soil erosion losses are obtained for grid sizes less than about 0.125 km². The analysis of the Conca de Tremp basin validates the use of the grid size factor proposed by Julien & Frenette (1987). It is also found that the grid size factor primarily depends on the average slope gradient which decreases with increasing grid size or drainage area. On the other hand, the grid size factor does not depend on the spatial variability of the factors R, K, L and C.     

Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry

The compositional variation of clinopyroxene and the partitioning of major elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from 1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H₂O = 1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca, Mg, Fe²⁺ and Si and enriched in Na, Fe³⁺, Al (mainly Al^IV), and Ti. Di and Hd versus CaTs and CaFeTs form a continuous binary solid solution characterized by higher amounts of tschermakitic components with increasing cooling rate. Two parameters (DH = Di + Hd and TE = CaTs + CaFeTs + En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions.Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of ^cpx–meltKd_Fe–Mg remain almost constant. Therefore, the Fe²–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic cooling magmas, giving rise to possible mismatches in the application of thermobarometers. The results of our study are consistent with that observed at the margin of dikes or in the exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.     

Multi-stage Melting in the Lower Crust of the Serre (Southern Italy)

The lower-crustal section exposed in the Serre, southern Italy,consists mainly of Al-rich metasediments, which underwent granulite-faciesmetamorphism, partial melting and melt extraction. The paperconsiders the formation of melts in metapelites and metagreywackes.Leucosomes and host rocks have been studied to investigate themelting process. Biotite-rich and biotite-free melanosomes withscarce felsic components are present; the biotite-rich typesare widespread in the upper part of the section and the twotypes may occur side by side in the lower part. Na-rich andK-rich leucosomes including residual phases are interspersedwithin the metasediments; on the whole they do not show geochemicalsignatures suggestive of magmatic fractionation. Leucotonalitictypes prevail among the sampled leucosomes, which generallyare rare earth element (REE) depleted with positive Eu anomalieswhereas the host rocks are REE enriched with overall negativeEu anomalies. Melanosomes and migmatites show restitic chemistries.The precursor metagreywackes underwent depletion in Na₂O andenrichment in K₂O. The precursor metapelites document generaldepletion in Na₂O and they may be enriched or depleted in K₂O.All the characteristics of the migmatites and of their componentsreflect a two-stage melting: (1) H₂O-present melting, involvingmainly plagioclase, and (2) dehydration melting of micas. Allthe metasediments underwent H₂O-present melting, forming mostlysodic melts which, owing to their removal from the source asfast as they formed, did not accumulate in such proportionsas to allow migration and mostly remained within the lower-crustalmetasediments; metapelites also underwent variable dehydrationmelting, depending on chemical features and physical conditions,forming larger volumes of mobile granitic melts, most of whichmigrated far from the source. Extractions of 57–66 vol.% of total melts (sodic + potassic) from the most residual metapeliticmelanosomes and of about 27–44 vol. % of potassic meltsfrom metapelitic migmatites have been calculated. Higher volumesof the extracted melts have been calculated for the metapelitesof the lower part of the section; the most depleted metagreywackesunderwent melt extraction of about 9–13 vol. %. The two-stagemelting occurred during the prograde metamorphism and continuedduring the isothermal decompression. KEY WORDS: Calabria; lower crust; multi-stage melting     

Soil-landscape and climatic relationships in the middle Miocene of the Madrid Basin

The Miocene alluvial-lacustrine sequences of the Madrid Basin, Spain, formed in highly varied landscapes. The presence of various types of palaeosols allows assessment of the effects of local and external factors on sedimentation, pedogenesis and geomorphological development. In the northern, more arid, tectonically active area, soils were weakly developed in aggrading alluvial fans, dominated by mass flows, reflecting high sedimentation rates. In more distal parts of the fans and in playa lakes calcretes and dolocretes developed; the former were associated with Mg-poor fan sediments while the latter formed on Mg-rich lake clays exposed during minor lake lowstands. The north-east part of the basin had a less arid climate. Alluvial fans in this area were dominated by stream flood deposits, sourced by carbonate terrains. Floodplain and freshwater lake deposits formed in distal areas. The high local supply of calcium carbonate may have contributed to the preferential development of calcretes on the fans. Both the fan and floodplain palaeosols exhibit pedofacies relationships and more mature soils developed in settings more distant from the sediment sources. Palaeosols also developed on pond and lake margin carbonates, and led to the formation of palustrine limestones. The spatial distributions and stratigraphies of palaeosols in the Madrid Basin alluvial fans suggest that soil formation was controlled by local factors. These palaeosols differ from those seen in Quaternary fans, which are characterized by climatically induced periods of stability and instability.     

Dolomite–silica stromatolites in Miocene lacustrine deposits from the Duero Basin, Spain: the role of organotemplates in the precipitation of dolomite

This research provides an ancient analogue for biologically mediated dolomite precipitation in microbial mats and biofilms, and describes the involvement of highly structured extracellular polymeric secretion (EPS) templates in dolomite nucleation. The structure of EPS is shown to match the hexagonal–trigonal lattice geometry of dolomite, which favoured the epitaxial crystallization of dolomite on the organic substrate. This structure of EPS also matches the arrangement of silica nanospheres in opal, which further accounts for the organically‐templated formation of opal enabling the non‐replacive co‐existence of dolomite and silica. The study is focused on a 50 m thick dolomite succession that is exposed in central areas of the Tertiary Duero Basin and was deposited in a mudflat‐saline lake sedimentary complex during the Middle to Late Miocene (9 to 15 Ma). In the intermediate intervals of the succession, poorly indurated dolomite beds pass gradually into silica beds. On the basis of sedimentological, compositional, geochemical and petrographic data, silica and dolomite beds have been interpreted as mineralized microbial mats. The silica beds formed in marginal areas of the lake in response to intense evaporative concentrations; this resulted in the rapid and early precipitation of opal. Silicification accounted for the exceptional preservation of the microbial mat structure, including biofilms, filamentous and coccoid microbes, and EPS. Extracellular polymeric secretions have a layered structure, each layer being composed of fibres which are arranged in accordance with a reticular pattern, with frequent intersection angles at 120° and 60°. Therefore, the structure of EPS matches the lattice geometry of dolomite and the arrangement of silica nanospheres in opal. Additionally, EPS binds different elements, with preference to Si and Mg. The concurrence of suitable composition and surface lattice morphologies in the EPS favoured the crystallization of dolomite on the substrate. In some cases, dolomite nucleation took place epicellularly on coccoid micro‐organisms, which gave way to spheroid crystals. Organic surfaces enable the inorganic mineral precipitation by lowering the free energy barrier to nucleation. Most of the microbial mats probably developed on the lake floor, under sub‐aqueous conditions, where the decomposition of organic matter took place. The subsequent formation of openly packed dolomite crystals, with inter‐related Si‐enriched fibrils throughout, is evidence for the pre‐existence of fibrillar structures in the mats. Miocene dolomite crystals are poorly ordered and non‐stoichiometric, with a slight Ca‐excess (up to 5%), which is indicative of the low diagenetic potential the microbial dolomite has towards a more ordered and stoichiometric structure; this confirms that microbial imprints can be preserved in the geological record, and validates their use as biosignatures.